Carbohydrates
Carbohydrates are aldehyde or ketone derivatives of
polyhydric aclcohols or any substance derived from them.
Importance of carbohydrates :
Carbohydrates are widely
distributed both in plants and in animal tissues.In plnts,
they are produced by
photosynthesis.Carbohydrate constitute about 60% of our diet .they are
important for:
- Energy production e.g. glucose.
- formation of structural elements in animal and plant cells.
- formation of glycolipids (Carbohydrates combined with lipids) and glycoproteins (Carbohydrates combined with protein) both enter in the structure of cell membrance .
Classification of carbohydrates :
- Monosaccharides : contain one sugar unit
- Disaccharides :contain two sugar units
- Oligosaccharides : contain 3-10 sugar unit
- Polysaccharides : contain more than 10 sugar unit
Monosaccharides
* They are the simple units of
carbohydrate i.e. on hydrlysis ,they can not give a simpler from The genral
formula is Cn (H2O)n .
- Naming (nomenclature) of
monosaccharides:
According to the presence of aldehyde or ketone group:
ketoses : monosaccharides containing ketone group (- c = o)Aldoses : monosaccharides containing aldehyde group (- CHO). The suffix – ose means sugar .
According to the number of carbon atoms:
- Trioses : monosaccharides containing 3 carbons
- Tetroses : monosaccharides containing 4 carbons
- pentoses : monosaccharides containing 5 carbons
- Hexoses : monosaccharides containing 6 carbons
- Heptoses: monosaccharides containing 7 carbons
According to both presence of aldehyde or ketone group and number of carbon atoms :
- Aldotrioses and ketotrioses
- Aldotetroses and ketotetroses
- Aldopentoses and ketopentoses
- Aldohexoses and ketohexoses
Classification of monosaccharide :
Trioses : monosaccharide containing 3 carbons
- Aldotrioses : Glyceraldehyde "
- ketotrioses:Dihydroxyacetone
Tetroses : monosaccharides containing 4 carbon atoms :
- Aldotetroses : Erythrose
- ketotetrose : Erythulose
pentoses : monosaccharides containing 5 carbon atoms
- Aldopentoses :Ribose , arabinose and xlyose
- Ketopentoses : Ribuose and xylulose
Hexoses :monosaccharides containing 6 carbon atoms
- Aldohexoses :glucose , mannose and galactose
- Ketohexose :fructose
Importance (functions) of pentoses :
- Ribose and deoxyribose enter in the structure of nucleic acids RNA and DNA
- Ribose enter in the structure of ATP, GTP and other high energy phosphate compounds
- Ribose enter in the structure of coenzymes NAD,NADP and flavoproteins
- Ribose phosphate and ribulose phosphate are intermediates in pentose phosphate pathway (a minor pathway for glucose oxidation).
- Arabinose and xylose are constituents of glycoproteins in plants and animals .
- Lyxose is constituent of lyxoflavin isolated from human heart muscle
- xylose is an intermediate in uronic acid pathway (a minor pathway for glucose oxidation )
Importance of Hexoses:
- Glucose is the most important sugar in carbohydrate : Dietary carbohydrates are absorbed in the form of glucose . In the liver and other tissues glucose is converted to all carbohydrates in the body e.g. glycogen / galactose / ribose and fructose .
- Glucose is the major source of energy in mammals
- Fructose fruit sugar .It can be converted into glucose in the liver + It is the main sugar of semen
- Galactose : It can be converted in to glucose in the liver . It is synthesized in mammary gland to make the lactose of milk (milk sugar)
- Mannose : A constituent of many glycoproteins
- Heptoses : As sedoheptulose (which is formed in the course of glucose oxidation (pentose phosphate pathway).
No comments:
Post a Comment