Polysaccharides
These are carbohydrates formed of
more than 10 sugar units . They are classified into : homopolysaccharides and heteropolysaccharides .
Homopolysaccharides:
They
contain repeated same sugar units and include :
- Starch
- Glycogen
- Cellulose
- Inulin
- Chitin
- Dextrans
Starch :
- Structure : Starch granule is formed of inner (a) and outher (b) layers:
- Inner layer:called amylase.It constitutes 15-20% of the granule and formed of non- branching helical Structure of glucose units linked together by a 1-4 glycosidic bond
- Outer layer: called amylopectin .It constitutes 80- 85% of the granule and formed of branched chain.
- Each chain is composed of 24-30 glucose units linked together by a 1-4 glycosidic bond and a 1-6 glycosidic bond at the branching points.
- Sources: It is the most important food source of carbohydrate ,it is found cereals, potatoes,legumes and other vegetables.
- proprties :
- Starch gives blue color with iodine.
- Partial hydrolysis (digestion)by amylase enzyme gives various forms of dextrins
Glycogen : (also called animal starch):
- Structure : It is highly branched chain homopolysaccharide. Each branch is composed of 12-14 glucose units ,linked together by a 1-4 glycosidic bonds and by a 1-6 glycosidic bond at branch point (like amylopectin) b.Sources: Glycogen is the storage form of carbohydrate in human and animals.It is synthesized and stored in liver , muscle and other tissues.
- proprties : It is gives reddish violet color with iodine .
Cellulose:
- Structure : It is long straight nonbranching chains of glucose units (b-D- glucopyranose)linked together by b 1-4 glycosidic bond.The chains are strengthening by cross linked hydrogen bonds .
- Sources: Cellulose is the chief constituent of the framework of plant leafy vegetables, fruits ,wood,cotton,etc
- proprties :
- Cellulose gives no color with iodine
- Cellulose is insoluble in water
- Many mammals including humans cannot digest cellulose of diet because of the absence of digestive hydrolase enzyme that attacks b- linkage
- However the present of cellulose in diet is important because it increase the bulk of stool.This stimulates intestinal movement and prevents constipation
- cellulose can be utilized and serve as a source of energy in herbivores because their gut contains bacterial enzyme than can attack b- linkage
Inulin :
- Structure : It is fructosan
i.e.formed of repeated units of fructose linked together by b 1-2 bonds.
- Sources: Root of plants
- proprties : Soluble in warm water
- Medical importance : Inulin clearance is one of diagnostic tests for investigation of glomerular filtration rate
Chitin :
- Structure : It is a polymer of N-acetylglucosamine liked together by b 1-4 glycosidic bonds
- Sources : It is important polysaccharide of invertebrates
Dextrans :
- Structure : It is branched chain homopolysaccharide .Each branch is composed of glucose units linked together by a 1-3 glycosidic bonds anda 1-6 glycosidic bond at branching point.
- Sources: dextran is synthesized from sucrose by certain bacteria .
- Functions : dextran is used as plasma substitute and prevents thrombosis.
- proprties : dextran is highly vicous and slowly degraded.
Galactosaans (agar- agar)
- They are condensation of galactose units present in agar (algae) .
- They are used to make cuture media .They are used medically to prevent constipation .
Heteropolysaccharides :
They contain repeated different
sugar units and include glycosaminoglycans proteoglcans and glycoproteins.
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